正癸烷+正戊醇,+1-己醇,+庚醇二元混合物在293.15到363.15K和大气压力下的密度和粘度(英文)
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【文章作者】Alejandro Estrada-Baltazar;Micael Gerardo Bravo-Sanchez;Gustavo Arturo Iglesias-Silva;Juan Francisco Javier Alvarado;Edgar Omar Castrejon-Gonzalez;Mariana Ramos-Estrada; |
【文章摘要】 Densities(ρ) and dynamic viscosities(η) for three binary mixtures of n-decane with 1-pentanol,1-hexanol and1-heptanol are presented at temperatures from 293.15 to 363.15 K and atmospheric pressure over the entire composition range.The density and viscosity are measured using a vibrating tube densimeter and a cylindrical Couette type rotating viscometer,respectively.Excess molar volumes(V~E),viscosity deviations(△η) and excess Gibbs energy of activation of viscous flow(△G~(*E)) are calculated from the experimental measurements.Intermolecular and structural interactions are indicated by the sign and magnitude of these properties.Partial molar volumes and infinity dilution molar partial volumes are also calculated for each binary system.These results are correlated using Redlich-Kister type equations. |
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【期刊】Chinese Journal of Chemical Engineering【卷】【ISSUE】【ISSUEID】
【文章期份】2015
【发布日期】2015/4/30 0:00:00
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