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Mechanism of generation of large(Ti,Nb,V)(C,N)-type precipitates in H13 + Nb tool steel
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| 【文章作者】You Xie;Guo-guang Cheng;Lie Chen;Yan-dong Zhang;Qing-zhong Yan; |
| 【文章摘要】 The characteristics and generation mechanism of(Ti,Nb,V)(C,N) precipitates larger than 2 μm in Nb-containing H13 bar steel were studied. The results show that two types of(Ti,Nb,V)(C,N) phases exist—a Ti-V-rich one and an Nb-rich one—in the form of single or complex precipitates. The sizes of the single Ti-V-rich(Ti,Nb,V)(C,N) precipitates are mostly within 5 to 10 μm, whereas the sizes of the single Nb-rich precipitates are mostly 2–5 μm. The complex precipitates are larger and contain an inner Ti-V-rich layer and an outer Nb-rich layer. The compositional distribution of(Ti,Nb,V)(C,N) is concentrated. The average composition of the single Ti-V-rich phase is(Ti_(0.511)V_(0.356)Nb_(0.133))(CxNy), whereas that for the single Nb-rich phase is(Ti_(0.061)V_(0.263)Nb_(0.676))(C_xN_y). The calculation results based on the Scheil–Gulliver model in the Thermo-Calc software combining with the thermal stability experiments show that the large phases precipitate during the solidification process. With the development of solidification, the Ti-V-rich phase precipitates first and becomes homogeneous during the subsequent temperature reduction and heat treatment processes. The Nb-rich phase appears later. |
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【期刊】International Journal of Minerals Metallurgy and Materials【卷】【ISSUE】【ISSUEID】
【文章期份】2016
【发布日期】2017/2/18 0:00:00
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