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Composition Dependence of the Thermal Behavior,Morphology and Properties of Biodegradable PBS/PTMO Segment Block Copolymer
【文件类型】 【消费金额】2.4 【文章页数】8 【会员操作】  
【文章作者】黄勇;LIU Junhong;周涛;张爱民;
【文章摘要】      A series of aliphatic biodegradable poly(ether-ester)s based on poly(butylene succinate)(PBS)as hard segment and poly(tetramethylene oxide)(PTMO,M_n=1 000 g/mol) as soft segment were synthesized.The composition dependence of thermal behavior,morphology and mechanical properties was investigated by differential scanning calorimetry(DSC),atomic force microscopy(AFM),and tensile testing.The crystallization temperature(T_c) and melting temperature(T_m) of the PBS block within poly(ether-ester)s decrease steadily at first,but decrease sharply with PTMO content above 50 wt%.Two crystallization peaks were detected for PTMO in PBSPTMO60 sample,suggesting the occurrence of fractionated crystallization.The crystallization enthalpies(△H_c) and melting enthalpies(△H_m) of PBS block decrease at first,then increase as PTMO content increases further.AFM has demonstrated that phase-separated morphology transforms from a phase of continuous hard matrix to one of continuous soft matrix containing isolated hard domain as PTMO content is increased.Finally,the results of tensile testing show that the poly(ether-ester)s present the behavior of plastics when PTMO content is below 40 wt%,and of thermoplastic elastomers with PTMO content above 50 wt%.By varying the composition of copolymer,the aliphatic poly(ether-ester)s plastics,or especially biodegradable aliphatic poly(ether-ester)s thermoplastic elastomers can be obtained.
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【期刊】【卷】【ISSUE】【ISSUEID】    【文章期份】2016    【发布日期】2016/3/15 0:00:00    点击率:1    打印    关闭
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