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Influence of Nano-Nd_2O_3 on Crystallization Mechanism of Fused Quartz
【文件类型】 【消费金额】1.8 【文章页数】6 【会员操作】  
【文章作者】GU Yinglei;BU Jinglong;CHEN Yuejun;MA Chao;WANG Zhifa;
【文章摘要】      The isothermal crystallization kinetics of pure fused quartz of blank specimen N- 0 and specimen N- 3 in troduced with 3 mass% nano-Nd2O3 was researched by means of XRD and Avrami equation. The results show that crystallization mechanisms of fused quartz in two specimens are both heterogeneous nucleation type caused by surface structure defects,and the grain growth mode of two specimens are both two-dimensional growth ac companied by one-dimensional and three-dimensiona growths,specimen N- 3 has the higher degree of grain growth in one-dimensional and three-dimensional than specimen N- 0; introducing nano-Nd2O3 can obviously reduce the "active nucleation sites"of glass structure on the fused quartz particles surface,enhance the stability o glass structure,increase the activation energy of fused quartz crystallization from 874 k J · mol- 1to 1 270 k J·mol- 1,and decrease the crystallization rate of fused quartz obviously.
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【期刊】China's Refractories【卷】【ISSUE】【ISSUEID】    【文章期份】2015    【发布日期】2016/1/8 0:00:00    点击率:1    打印    关闭
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